Product ID:775655 17, EN ALKYD, SEMI-GLOSSLO VOC CT GRAY(SUPDAT)
MSDS Date:06/30/1993
FSC:8010
NIIN:01-019-7945
MSDS Number: BWCFW

PRATT & LAMBERT INC

WICHITA, KS 67201
US

Emergency Phone: 716-873-6000

Info Phone: 318-733-1361

Preparer: MARTIN MARIETTA

Cage: PRATT

PRATT AND LAMBERT INC

2153 CLEVELAND, OH 44101-1027 US

Telephone: 216-566-2902

Cage: 61196

7%.

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 10%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III).

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 5%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM;200 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 15%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

SILICA GEL; (SILICA, AMORPHOUS HYDRATED)

CAS: 112945-52-5

RTECS: VV7310000

Fraction By Weight: 5%

OSHA PEL 6 MG/M3

ACGIH TLV: 10 MG/M3

TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)

CAS: 14807-96-6

RTECS: WW2710000

Fraction By Weight: 20%

OSHA PEL 2 MG/M3 RDUST

ACGIH TLV: 2 MG/M3 RDUST

SILICA, CRYSTALLINE - QUARTZ; (SILICA, CRYSTALLINE)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <1%

OSHA PEL 10 MG/M3 RDUST

ACGIH TLV: 0.1 MG/M3 RDUST

2-HEXANONE, 5-METHYL-; (METHYL ISOAMYL KETONE)

CAS: 110-12-3

RTECS: MP3850000

Fraction By Weight: 5%

OSHA PEL 50 PPM (MFR)

ACGIH TLV: 50 PPM

70

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 5%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM;300 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2.97 LB/GAL, 356 G/L (LESS

RTECS: 9999999VO

PRLNG & RPTD OCCUP OVEREXP TO SOLVS W/PERM BRAIN &

RTECS: 9999999ZZ

CONTENTS MAY BE HARMFUL/FATAL. DRY TITANIUM DIOXIDE

RTECS: 9999999ZZ

INCR IN BENIGN & MALIGNANT LUNG TUMORS IN GRP EXPOS

RTECS: 9999999ZZ

MECHS OF LUNGS MAY HAVE BEEN OVERWHELMED AT 250

RTECS: 9999999ZZ

FORM. THERE RSLTS MAY NOT BE DIRECTLY RELEVANT TO

RTECS: 9999999ZZ

STUDIES INVOLVING RATS INDICATE SOME EVID THAT

RTECS: 9999999ZZ

ANY TREATMENT THAT MIGHT BE REQD

RTECS: 9999999ZZ

& CLINICAL CONDITIONS.

RTECS: 9999999ZZ

USE ONLY NON-SPARKING TOOLS. PLACE ABSORB DIKING

RTECS: 9999999ZZ

OF SEWERS, STREAMS & GROUNDWATER W/SPILLED MATL OR

RTECS: 9999999ZZ

RESTRICTED VENT AREAS NIOSH/MSHA APPRVD CHEM

RTECS: 9999999ZZ

SPRAYING, MECH PREFILTER MAY ALSO BE REQD. IN

RTECS: 9999999ZZ

TLV'S ARE EXCEEDED USE PROPERLY FITTED NIOSH/MSHA

RTECS: 9999999ZZ

1910.134 "RESP PROT" & "RESP PROT MANUAL &

RTECS: 9999999ZZ

MAY BE LISTED. REFER TO "INDUS VENT - A MANUAL FOR REC

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:CAN CAUSE GI IRRIT, NAUS
& VOMIT. ASPIR OF MATL INTO LUNGS MAY CAUSE CHEM PNEUM WHICH CAN BE
FATAL. INHAL:MAY CAUSE NOSE/THROAT IRRIT. HIGH CONCS MAY CAUSE
ACUTE CNS DEPRESS CHARACT BY HD CHS, DIZZ, NAUS & CONFUSN. EYE:MAY
CAUSE SEV IRRIT. SKIN:LIQ MATL MAY BE ABSORBED IN HARMFUL AMTS. MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ:CAUSE DEFAT & IRRIT. CHRONIC:RPTD &
PRLNG OCCUP OVEREXP TO CRYSTALLINE SILICA MAY CAUSE SILICOSIS,
PROGRESSIVELY DIABLING LUNG DISEASE. OVEREXP TO XYLENE MAY CAUSE
INJURY TO LIVER, KIDNEYS & BLOOD. EXPOS TO METHYL ETHYL KETONE
MAYINHANCE NEUROTOX OF N-HEXANE & METHYL-N-BUTYL KETONE. THIS
SYNERGISTIC (SUPDAT)
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.

First Aid:INGEST:DO NOT INDUCE VOMIT. CALL POIS CTL CTR, HOSPITAL EMER
ROOM/MD IMMED. INHAL:REMOVE TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED, GIVE ARTF RESP. KEEP WARM & QUIET. GET MED ATTN IMMED.
EYE:FLUSH W/LG AMTS OF WATER, LIFTING UPPER & LOWER LIDS OCCAS.
CONTINUE FOR AT LST 15 MINS. GET MED ATTN. SKIN:REMOVE CONTAM
CLTHG. WASH AFFECTED AREA W/SOAP & WATER. OBTAIN MED ATTN IF IRRIT
PERSISTS. (ING 16)

Flash Point:24.0F,-4.4C
Lower Limits:SEE INGS
Upper Limits:SEE INGS
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGS (CARBON DIOXIDE, ALL
PURPOSE DRY CHEM/ALCOHOL FOAM) DESIGNED TO EXTING FLAMM LIQ
(SUPDAT)
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER MAY BE INEFT, BUT MAY BE USED TO COOL EXPOS CNTNRS TO PVNT
PRESS BUILD-UP & POSS AUTO-IGNIT/ (SUPDAT)
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE
IMMED APPARENT. OBTAIN MED ATTN. WARNING - FLAMMABLE.

Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM ALL IGNIT
SOURCES(FLAMES, HOT SURFS & SOURCES OF ELEC, STATIC/FRICTIONAL
SPKS). DIKE & CONTAIN SPILL W/INERT MATL(E.G. SAND, EARTH).
TRANSFER LIQS TO COVERED METAL CNTNRS FO R RECOVERY/DISP, OR REMOVE
W/INERT ABSORB.(ING 18)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE >115F (46C). STORE LG
QTYS IN COMPLIANCE W/OSHA 29 CFR 1910.106. DO NOT TAKE INTERNALLY.
CLOSE CNTNR AFTER EACH USE.
Other Precautions:DO NOT BREATHE SANDING DUST. EMPTY CNTNRS MUST NOT BE
WASHED & RE-USED FOR ANY PURPOSE. CNTNRS SHOULD BE GROUNDED &
BONDED TO RECEIVING CNTNR. DO NOT WELD, BRAZE/CUT EMPTY CNTNR.
NEVER USE PRESS TO EM PTY. DRUM IS NOT A PRESS VESSEL.

Respiratory Protection:PROPER SELECTION OF RESP PROT DEPENDS UPON MANY
FACTORS INCL DURATION/LEVEL OF EXPOS & CNDTNS OF USE. IN GEN EXPOS
TO ORG CHEMS SUCH AS THOSE CNTND IN THIS PROD MAY NOT REQ USE OF
RESP PROT IF USED IN WELL VENTILATED AREAS. IN (ING 20)
Ventilation:PROVIDE LOC EXHST VENT IN SUFFICIENT VOL & PATTERN SO AS TO
MAINTAIN EXPOS BELOW NUISANCE DUST LIMS & PELS WHICH(ING 24)
Protective Gloves:SOLVENT IMPERMEABLE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:NOT LIKELY TO BE NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:26492 TT-E-529G. EXTING MEDIA:FIRES. POLYMER
FOAM IS PREF FOR LG FIRES. FIRE FIGHT PROC:EXPLO WHEN EXPOS TO
EXTREME HEAT. IF WATER IS USED, FOG NOZZ ARE PREF. EXPLAN OF CARCIN
:1994:ANTIC TO BE CARCIN. EFTS OF OVEREXP:EFTS HAS RSLTD IN
PERIPHERAL NEUROPATHY IN HUMANS. RPTS HAVE ASSOC (ING 10)

Boiling Pt:B.P. Text:>175F,>79C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.4
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:41

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115F (46C)) &
SOURCES OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE & CARBON
DIOXIDE.

Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS. THIS PRODUCT, IF DISCARDED DIRECTLY, WOULD BE
CLASSIFIED HAZ WASTE BASED ON ITS IGNITABILITY CHARACT, I.E. HAS
FLASH POINT OF 140F (60C) OR LESS. HAZ WASTE #:D001.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.